Category MI L20 Diatoms: Nature's Nano Architects

Abstract Diatoms are unicellular organisms, and are considered to be some of

nature’s finest architects. Diatoms engineer intricate shells of amorphous

silica on the nanometer scale. However, little is known about how such

detailed construction is carried out at such a small scale. Due to their

photosynthetic capabilities and abundance, diatoms have a profound

impact on the delicate equilibrium of the environment. They account for

approximately 45% of the Earth’s oceanic energy production, and are

responsible for nearly 20% of global carbon fixing capacity. Therefore,

understanding the unique cellular processes of diatoms will provide us

with new insights into mineral deposition in larger animals, such as the

deposition of bone in humans. Since different species of diatoms construct

markedly different exoskeletons, I hypothesized that species-specific soft

proteinaceous structures may exist in diatoms, controlling and regulating

the precise deposition of silica. In the current study, I provide evidence for

the first time of a pore like protein complex in the Thalassiosira

pseudonana diatom cell membrane, explored using atomic force

microscopy. The primary objective of this study was to understand the

precise mechanism of the deposition of the silica exoskeleton, or frustule,

in diatoms. Preceding the formation of the silica structure, silica in the form

of silicic acid is taken in by the diatom from its environment and collected in

a large vesicle. The vesicle docks at the cell membrane and releases its

contents to form the shell of the diatom. The molecular mechanism of

release and arrangement of the frustule was the focus of the study. Using

high-resolution electron and atomic force microscopy, both the frustules

and the cell membranes of diatoms were examined. Examination using

AFM yielded a circular protein complex on the diatom cell membrane. T-

SNARE s or target proteins are proteins that are required for the secretory

vesicle docking and fusing process in cells. Western blots were used to

validate the presence of T-SNARE proteins in diatoms, and T-SNAREs

were consistently found in analyses of centrifuged diatom pellets. The

“pore” structure was positively identified as the silica secretory machinery

in this unicellular organism. Further analysis of this complex could yield the

answers to many questions, including the details of the deposition of

mineralized osseous tissue in vertebrate bone structure. New frontiers in

the rapidly expanding field of biological mimicry or biomimetics would be

established, especially in nano-scale processes such as drug delivery, the

development of catalysts for use in industry, and even nano electronics

and robotics. Furthermore, the large role that diatoms play in our

environment will allow us to use the knowledge gained from such studies

to reverse many of the negative impacts of environmental pollution to our

planet, and the use of diatoms as an energy source and for global carbon

fixation.

Bibliography Almqvist N, Delamo Y, Smith BL, Thomson NH, Bartholdson A, Lal R. et al.

Micromechanical and structural properties of a pennate diatom investigated

by atomic force microscopy. J. Microsc. 2001; 202: 518-532.Blank GS,

Sullivan CW. Diatom mineralization of silicic acid VI. The effects of

microtubule inhibitors on silicic acid metabolism in Navicula saprophila. J

Phycol. 1983; 19: 39-44.
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